Intrinsic glassy-metallic transport in an amorphous coordination polymer
Heeger, AJ Nobel Lecture: Semiconductor and Metallic Polymers: The Fourth Generation of Polymer Materials. Rev. mod. Phys. 73681–700 (2001).
Bryce, MR Recent advances in conducting charge transfer organic salts. Chem. Soc. Round. 20355 (1991).
Valade, L., de Caro, D., Faulmann, C. & Jacob, K. TTF[Ni(dmit)2]2: from single crystals to thin layers, nanowires and nanoparticles. Coord. Chem. Round. 308433–444 (2016).
Xie, LS, Skorupskii, G. & Dincă, M. Metal-organic frameworks that conduct electricity. Chem. Round. 1208536–8580 (2020).
Guo, X. & Facchetti, A. The journey of conductive polymers from discovery to application. Nat. Mater. 19922–928 (2020).
Bubnova, O. et al. Semi-metallic polymers. Nat. Mater. 13190-194 (2014).
Kobayashi, A., Fujiwara, E. & Kobayashi, H. Single component molecular metals with extended TTF dithiolate ligands. Chem. Round. 1045243–5264 (2004).
Kobayashi, Y., Terauchi, T., Sumi, S. & Matsushita, Y. Carrier generation and electronic properties of a pure single-component organic metal. Nat. Mater. 16109-114 (2017).
Venkateshvaran, D. et al. Approach to disorder-free transport in high-mobility conjugated polymers. Nature 515384–388 (2014).
Joo, Y., Agarkar, V., Sung, SH, Savoie, BM & Boudouris, BW An unconjugated radical polymeric glass with high electrical conductivity. Science 3591391–1395 (2018).
Plummer, J. Is metallic glass about to come of age? Nat. Mater. 14553-555 (2015).
Hirata, A. et al. Geometric frustration of the icosahedron in metallic glasses. Science 341376–379 (2013).
Eisenberg, R. & Gray, HB Noninnocence in Metal Complexes: A Dawn of Dithiolene. Inorg. Chem. 509741–9751 (2011).
McCullough, RD et al. Ligands building blocks for new molecular conductors: homobimetallic tetrathiafulvalene tetrathiolates and metallic diselenolenes and ditellurolenes. J. Mater. Chem. 51581 (1995).
Xie, J. et al. Redox, transmetallation and stacking properties of tin, nickel and palladium compounds bridged by tetrathiafulvalene-2,3,6,7-tetrathiolate. Chem. Science. 111066-1078 (2020).
de Caro, D. et al. TTF Metallic Thin Films[Ni(dmit)2]2 by electrodeposition on oriented silicon substrates (001). Adv. Mater. 16835–838 (2004).
Scott, RA Comparative X-ray Absorption Spectroscopic Structural Characterization of Nickel Metalloenzyme Active Sites. Phys. B Condens. Question 15884–86 (1989).
Holder, CF & Schaak, RE Tutorial on X-ray powder diffraction to characterize materials at the nanoscale. ACS Nano 137359–7365 (2019).
Tanaka, H., Okano, Y., Kobayashi, H., Suzuki, W. & Kobayashi, A. A three-dimensional synthetic metallic crystal composed of single-component molecules. Science 291285–287 (2001).
Vogt, T. et al. A LAXS (large sngle X-ray dcattering) and EXAFS (extended X-ray absorption fine structure) study of conductive amorphous nickel tetrathiolato polymers. Jam. Chem. Soc. 1101833–1840 (1988).
Liu, Z et al. Control of the thermoelectric properties of organometallic coordination polymers through the design of ligands. Adv. Function Mater. 302003106 (2020).
Choy, CL, Leung, WP & Ng, YK Thermal conductivity of metallic glasses. J.Appl. Phys. 665335–5339 (1989).
Sun, L. et al. A microporous, naturally nanostructured thermoelectric organo-metallic network with ultra-low thermal conductivity. Joule 1168-177 (2017).
Craven, GT & Nitzan, A. Wiedemann–Franz Law for molecular hopping transport. Nano Lett. 20989–993 (2020).
Dou, JH et al. Signature of metallic behavior in organometallic frameworks M3(hexaiminobenzene)2 (M = Ni, Cu). Jam. Chem. Soc. 13913608–13611 (2017).
Kaiser, AB Electronic transport properties of conductive polymers and carbon nanotubes. Program Reports. Phys. 641–49 (2001).
Halim, J. et al. Variable range hopping and thermally activated transport in molybdenum-based MXenes. Phys. Rev. B 98104202 (2018).
Lan, X et al. Quantum dot solids showing state-resolved band-like transport. Nat. Mater. 19323–329 (2020).
Kang, SD, Dylla, M. & Snyder, GJ Thermopower-conductivity relationship to distinguish transport mechanisms: polaron jump in CeO2 and band conduction in SrTiO3. Phys. Rev. B 97235201 (2018).
Heeger, AJ Disorder-induced metal-insulator transition in conductive polymers. J. Supercond. 14261–268 (2001).
Jiang, Y. et al. Synthesis of a metallic-organic copper compound 1,3,5-triamino-2,4,6-benzenetriol. Jam. Chem. Soc. 14218346–18354 (2020).
Lee, K. et al. Polyaniline metal transport. Nature 44165–68 (2006).
Mazziotti, DA Large-scale semi-definite programming for many-electron quantum mechanics. Phys. Rev. Lett. 106083001 (2011).
He, T., Stolte, M. & Würthner, F. Air-stable n-channel organic single-crystal field-effect transistors based on core chlorinated naphthalene diimide microstrips. Adv. Mater. 256951–6955 (2013).
Huang, X. et al. Superconductivity in a copper(II)-based coordination polymer with a perfect Kagome structure. Angelw. Int. Chemistry Ed. 57146-150 (2018).
Gill, NS & Nyholm, RS Complex halides of transition metals. Part I. Tetrahedral nickel complexes. J. Chem. Soc. 19593997–4007 (1959).
Ravel, B. & Newville, M. ATHENA, ARTEMIS, HEPHAESTUS: Data analysis for X-ray absorption spectroscopy with IFEFFIT. J. Synchrotron radiation. 12537–541 (2005).
Rehr, JJ & Albers, RC Theoretical approaches to X-ray absorption fine structure. Rev. Mod. Phys. 72621–654 (2000).
Toby, BH & Von Dreele, RB GSAS-II: the genesis of a modern open-source general-purpose crystallography software package. J.Appl. Crystallologist. 46544–549 (2013).
Yang, X., Juhas, P., Farrow, CL & Billinge, SJL XPDFsuite: An end-to-end software solution for high-throughput pair distribution function transformation, visualization, and analysis. https://arxiv.org/abs/1402.3163 (2014).
Morrison, C., Sun, H., Yao, Y., Loomis, RA, and Buhro, WE Methods for ICP-OES Analysis of Semiconductor Materials. Chem. Mater. 321760-1768 (2020).
Ma, T., Dong, BX, Grocke, GL, Strzalka, J. & Patel, SN Leveraging sequential doping of semiconductor polymers to enable functionally graded materials for organic thermoelectrics. Macromolecules 532882–2892 (2020).
Giannozzi, P. et al. QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials. J.Phys. Condens. Question 21395502 (2009).
Giannozzi, P. et al. Advanced features for material modeling with Quantum ESPRESSO. J.Phys. Condens. Question 29465901 (2017).
Marzari, N., Vanderbilt, D., De Vita, A. & Payne, MC Thermal contraction and disorder of the Al(110) surface. Phys. Rev. Lett. 823296–3299 (1999).
Prandini, G., Marrazzo, A., Castelli, IE, Mounet, N. & Marzari, N. Accuracy and efficiency in solid-state pseudopotential calculations. NPJ calculation. Mater. 472 (2018).
Lejaeghere, K. et al. Reproducibility in the calculations of the functional theory of the density of solids. Science 351aad3000 (2016).
Kokalj, A. XCrySDen – a new program for displaying crystal structures and electron densities. J.Mol. Chart. Model. 17176–179 (1999).